Sailor ChibiMoon's Anime Forms
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ChibiUsa Tsukino
ChibiUsa appears in episode 060. She comes from the future Crystal Tokyo, where she is the daughter of Neo Queen Serenity (future form of Usagi) and King Endymion (future form of Mamoru). Her full name is "Usagi Tsukino," having been named after her mother, but is usually called ChibiUsa.

Black Lady
In episode 085, Wiseman fills ChibiUsa's head with exaggerations, twisting and warping her memories to the point that she believes that no one loves her. She grows into the evil Black Lady, and attempts to destroy the senshi. Eventually, Sailor Moon transforms into Neo Queen Serenity and revives ChibiUsa's memories so that she reverts back to her normal form.

Small Lady
In episode 88, the Maboroshi no Ginzuishou of the future appears in ChibiUsa's tear. She asks for its help, and is immediately transformed into her princess form, as Small Lady. Together with Neo Queen Serenity and the Ginzuishou of the past, they destroy Wiseman.

Sailor ChibiMoon
In the third season of Sailor Moon, ChibiUsa returns to the past to train as a soldier with the Sailor Senshi (per Neo Queen Serenity's request). We first see her as Sailor ChibiMoon, the soldier-in-training, in episode 103.

Super Sailor ChibiMoon
In episode 128, the first episode of the fourth season, Pegasus appears to ChibiUsa in her dreams. Later in the episode, she wishes that someone would help her and Sailor Moon, lest they die at the hands of the enemy. Suddenly, Pegasus appears before them and allows them to transform into Super Sailor Moon and Super Sailor ChibiMoon. Later on, he gives the two new brooches with which to transform.

Adult ChibiUsa
In episode 158, PallaPalla uses her magic to switch the ages of Sailor Moon and Sailor ChibiMoon - Sailor Moon becomes a child, while Sailor ChibiMoon becomes an adult. Eventually, Sailor ChibiMoon returns them to their normal bodies.